Page 50 - 《橡塑技术与装备》2025年10期
P. 50
橡塑技术与装备
HINA R&P TECHNOLOGY AND EQUIPMENT
the structure, dynamic mechanical and thermal properties [14] 郑鹏程,胡琳,焦旗,等 . 有机成核剂改性聚丙烯的研究 [J].
of polypropylene ( 聚丙烯 )[J]. Iranian Polymer Journal, 现代塑料加工应用 , 2018,30(06):31-34.
2015,24(10). [15] 彭文理,宗鹏,张文学,等 . 聚丙烯 β 成核剂的研究进展 [J].
[4] Rasana N, Murugan S, Rammanoj G, et al. The Effect of 工程塑料应用,2017,45(11):131-135.
Different Nanofillers on the Morphology, Mechanical, [16] 蒋海斌,张晓红,乔金樑 . 聚烯烃结晶成核剂的研究进展 [J].
Sorption and Thermal Properties of Polypropylene based 石油化工 , 2011,40(10):1 027-1 036.
Hybrid Composites[J]. Materials Today: Proceedings, [17] 郑鹏程,胡琳,焦旗,等 . 有机成核剂改性聚丙烯的研究 [J].
2020,24(Pt 2). 现代塑料加工应用,2018,30(06):31-34.
[5] Luo G, Liu G, Chen Y, et al. High performance glass fiber [18] 郭敏 . 有机成核剂的复配及其在聚丙烯中超细化分散的研究
reinforced polypropylene realized by reactive extrusion [D]. 北京理工大学,2014.
t e c hnol ogy[J]. Com posi t e s Sc i e nc e a nd Te c hnol ogy, [19] 王卫霞,周帅,辛忠,等 . 山梨醇类成核剂对改性聚丙烯发泡
2018,165. 性能的影响 [J]. 中国塑料,2016,30(05):87-92.
[6] Yuanm ing Z, Ti ngting S, Wei J, et al. Crystalli ne [20] Yang G, Li X, Yang J, et al. Crystallization behavior of
modification of a rare earth nucleating agent for isotactic sorbitol derivative nucleated polypropylene block copolymer
polypropylene based on its self-assembly.[J]. Royal Society under high pressure[J]. Colloid and Polymer Science,
open science, 2018,5(5). 2013,291(9).
[7] 刘晓霞 , 周惠 , 张普玉 . 聚丙烯成核剂研究进展 [J]. 塑料工业 , [21] 孙天伟,李娟,于杰,等 . 有机磷酸盐类成核剂对聚丙烯性能
2006(02):1-3. 的影响 [J]. 塑料工业,2017,45(06):130-133.
[8] 曹莉,李青, 苏志强, 等 . 聚丙烯成核剂研究进展 [J]. 高分子 [22] Zhang G, Xin Z, Yu J, et al. Nucleating Efficiency of
通报,2013(04):146-150. Organic Phosphates in Polypropylene[J]. Journal of
[9] 胡成浪,张才亮, 盛仲夷 . 成核剂改性共聚聚丙烯的研究进展 Macromolecular Science, Part B, 2003,42(3-4).
[J]. 塑料助剂,2020(02):1-6. [23] 陈廷辉,王亚明,潘登,等 . 松香基成核剂的研究及应用进展
[10] 孟鑫,公维光,伍楚诗,等 . 改性滑石粉协同磷酸酯钠盐调控 [J]. 化工进展,2017,36(08):3 040-3 046.
制备高刚、耐热聚丙烯 [J]. 塑料助剂,2018(01):30-34. [24] 王显华 . 皂化松香的应用研究综述 [J]. 广东化工,
[11] 李谷,梁庭安,李赫,等 . 云母与成核剂复配改性聚丙烯 [J]. 2011,38(03):30-31.
合成树脂及塑料 , 2010,27(01):27-29. [25] Hamada K. Uchiyama H.US.4016118.1977
[12] Li Y, Wang S, Zhang Y, et al. Crystallization behavior of [26] ICI Chemical Co Ltd. JP, 32420. 1970.
carbon black‐filled polypropylene and polypropylene/epoxy [27] 史观一,张景云 .β 晶型聚丙烯的研究 [J]. 科学通报,
composites[J]. Journal of A 聚丙烯 lied Polymer Science, 1981(12):731-733.
2006,102(1). [28] 水恒毅,王益龙,张帆,等 . 各种羧酸二盐对嵌段共聚聚丙烯
[13] 杨雪芹,葛志华,韩捷,等 . 硅胶接枝 1,3-2,4-二(对甲基 的 β 成核研究 [J]. 现代塑料加工应用,2011,23(04):49-52.
亚苄基 ) 山梨醇成核剂的制备 [J]. 合成树脂及塑料,2019,36
(01):38-42.
Progress in the application of nucleating agents for polypropylene
Yu Yang, Shen Guoliang, Xu Tiejun*, Wen Ruiyang
(School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang 111003, Liaoning, China)
Abstract: With the continuous expansion of polypropylene (PP) application fields and the sustained
growth of production demand, optimizing the properties of polypropylene has become a hot topic in
academic research. Adding nucleating agents for modification is an extremely effective method, and the use
of nucleating agents significantly improves the mechanical properties, mechanical properties, transparency,
and ductility of polypropylene. This article summarizes the main types of polypropylene nucleating agents,
including inorganic nucleating agents and organic nucleating agents. Given that organic nucleating
agents are superior to inorganic nucleating agents in terms of chemical stability, the article focuses on the
production process and application methods of organic nucleating agents, and based on current research
and development progress, it provides an outlook on the future development direction of polypropylene
nucleating agents.
Key words: polypropylene; nucleating agent; PP; crystallization
(R-03)
·4· 第 51 卷 第 10 期