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综述与专论 张伟 等·二维纳米催化剂的研究进展与展望

在光催化方面，光激发下半导体催化剂的带隙是一个 edge sites for electrocatalysis[J]. Journal of Materials
Chemistry, 2012, 11(2):963–969.
主导因素。目前，二维纳米材料和三维块状材料的维
[11] G. Wang, J. Tao, Y. Zhang. Engineering two-dimensional
度对于控制能带隙位置的基本机制和具体影响尚不清 m a ss- t ra n sp o rt c h a nn e l s o f t h e MoS2 n a n oc a t a l yst
楚。迄今为止，二维纳米材料的理论催化机制仍不容 toward improved hydrogen evolution performance[J].
Advanced Materials Interfaces, 2018, 32(10):25 409–25 414.
易适用于真实的复杂反应系统，因此对催化机制的更
[12] S. Zhang, B. Li, X. Wang. Recent developments of two–
多理论和基础研究值得探索。
dimensional graphene–based composites in visible-light
除了用于大规模生产的技术发展外，催化剂成型 photocatalysis for eliminating persistent organic pollutants
的能力也受到关注，以满足最终应用的需求。当二维 from wastewater[J]. Chemical Engineering Science, 2020,
39(25):124–132.
纳米材料以散装粉末的形式使用时，它们可能会团聚，
[13] W.Q. Qian, W.Y. Yang, Y. Zhang. Piezoelectric materials
限制了它们的应用。将二维纳米材料固定在基底上提 for controlling electro-chemical processes[J]. Nano-Micro
供了改善其易用性的有希望的方法。例如，二维纳米 Letters, 2020, 12(21):149–159.
[14] J. Wu, Z. Wu, W. Qian. Electricfield–treatment-induced
材料可以外延生长在其他材料的表面上，组装成泡沫
enhancement of photoluminescence in Er3+ – doped
状，或者支持在碳纤维纸或镍泡沫上以提高催化活性。 (Ba0.95Sr0.05)(Zr0.1Ti0.9)O3 piezoelectric ceramic[J].
Letters, 2016, 184(28):131–133.
[15] Y. Zheng, Y. Jiao, Y. Zhu. Molecule level g–C3N4 coordinat
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2024 第 50 卷 ·9·
年